My research in september:
-Study of stability of homogeneous citrate solutions by UV-Vis spectroscopy method, in the following solutions:
1) 0,25 M Na3HCit; pH=5;
2) 0,65 M Na3HCit; pH=5;
3) 0,65 M Na3HCit; 0,02 M Na2MoO4; pH=5;
4) 0,25 M Na3HCit; 0,02 M Na2MoO4; pH=5;
5) 0,65 M Na3HCit; 0,1 M Na2MoO4; pH=5;
6) 0,25 M Na3HCit; 0,1 M Na2MoO4; pH=5;
7) 0,65 M Na3HCit; 0,24 M Na2MoO4; pH=5;
8) 0,25 M Na3HCit; 0,24 M Na2MoO4; pH=5;
9) 0,65 M Na3HCit; 0,08 M SnSO4; pH=5;
10) 0,65 M Na3HCit; 0,24 M Na2MoO4; 0,08 M SnSO4; pH=5;
11) 0,65 M Na3HCit; 0,16 M ZnSO4; pH=5;
12) 0,65 M Na3HCit; 0,24 M Na2MoO4; 0,16 M ZnSO4; pH=5;
13) 0,65 M Na3HCit; 0,16 M ZnSO4; 0,08 M SnSO4; pH=5;
14) 0,65 M Na3HCit; 0,24 M Na2MoO4; 0,16 M ZnSO4; 0,08 M SnSO4; pH=5;
15) 0,65 M Na3HCit; 0,24 M Na2MoO4; 0,16 M ZnSO4; 0,08 M SnSO4; ¬0,12 M Na2SO3; pH=5;
- study of the complex formation and its stability in various citrate system by cyclic voltammetry with rotating disc electrode method , in the following solutions:
1) 0,65 M Na3HCit; pH=5;
2) 0,65 M Na3HCit; 0,24 M Na2MoO4; pH=5;
3) 0,65 M Na3HCit; 0,08 M SnSO4; pH=5;
4) 0,65 M Na3HCit; 0,24 M Na2MoO4; 0,08 M SnSO4; pH=5;
5) 0,65 M Na3HCit; 0,16 M ZnSO4; pH=5;
6) 0,65 M Na3HCit; 0,24 M Na2MoO4; 0,16 M ZnSO4; pH=5;
7) 0,65 M Na3HCit; 0,08 M SnSO4; 0,16 M ZnSO4; pH=5;
8) 0,65 M Na3HCit; 0,24 M Na2MoO4; 0,08 M SnSO4; 0,16 M ZnSO4; pH=5;
9) 0,65 M Na3HCit; 0,02 M C3H6O; pH=5;
10) 0,65 M Na3HCit; ¬0,12 M Na2SO3; pH=5;
11) 0,65 M Na3HCit; 0,24 M Na2MoO4; ¬0,12 M Na2SO3; pH=5;
12) 0,65 M Na3HCit; 0,08 M SnSO4; ¬0,12 M Na2SO3; pH=5;
13) 0,65 M Na3HCit; 0,24 M Na2MoO4; 0,08 M SnSO4; ¬0,12 M Na2SO3; pH=5;
14) 0,65 M Na3HCit; 0,16 M ZnSO4; ¬0,12 M Na2SO3; pH=5;
15) 0,65 M Na3HCit; 0,24 M Na2MoO4; 0,16 M ZnSO4; ¬0,12 M Na2SO3; pH=5;
16) 0,65 M Na3HCit; 0,08 M SnSO4; 0,16 M ZnSO4; ¬0,12 M Na2SO3; pH=5;
17) 0,65 M Na3HCit; 0,24 M Na2MoO4; 0,08 M SnSO4; 0,16 M ZnSO4; ¬0,12 M Na2SO3; pH=5;

Research in September:

- preparation of samples of AA1050 alloy to observations with the high resolution scanning electron microscopy equipped with the local orientation measurements facility - grinding, polishing;

- preparation of orientation maps of aluminum alloy after ECAP and recrystallization (new and constant time = 1h);

- analysis of microstructures after deformation and during recrystallization of AA1050 aluminium processed by equal-channel angular pressing (ECAP);

Conference:

- preparation of the presentation under the title: ‘Structural changes in recrystallization of AA1050 aluminium alloy processed by ECAP’ for the 39th School in Materials Science in Krynica;

- attending in 39th School in Materials Science (Krynica 27-30.09.2011).

Main studies carried out during September:

- preparation of thin foils by electropolishing from ribbons samples with vanadium, molybdenum, titanium, zirconium and chromium addition for observation with Transmission Electron Microscopy

- microstructure observation of melt-spun ribbon with Cr addition using TEM, determination of phases chemical composition

- participation in 10th Multinational Congress on Microscopy in Urbino in Italy (4-9.09.2011), during conference attendance in poster session with the poster: “TEM study of the quasicrystalline phase transformation in Al-Mn-Fe melt-spun ribbon”.

- preparation of the article and oral presentation for the 39th School in Materials Science in Krynica, with the title: “Microstructure, mechanical properties and thermal stability of Al-Mn-Fe melt-spun ribbons”.

- participation in 39th School in Materials Science in Krynica (27-30.09.2011), during session A (non-ferrous metal alloys) oral presentation was given with the title mentioned above

- preparation of article for Archives of Metallurgy and Materials with the title: “Characterization of as-spun and annealed Al-Mn-Fe ribbon”.

Whole month was spent on reading scientific literature about my topic. I was focused on the information about morfology and energies of grain boundaries in polycrystalline samples.

In 27-30.09.2011 in Krynica I attended in 39th School in Materials Science.
I presented the presentation (based on the article) during session A (non-ferrous metal alloys).
Below the abstract of mine article:

STRUCTURAL CHANGES IN RECRYSTALLIZATION
OF AA1050 ALUMINIUM ALLOY PROCESSED BY ECAP
J. Poplewska, A. Tarasek, K. Berent, H. Paul
Abstract
This paper describes the development of microstructure after deformation and during recrystallization of AA1050 aluminium processed by equal channel angular pressing (ECAP). The nucleation of new grains and further grain growth were observed in bulk samples after static recrystallization at 270°C. The samples were deformed along route A (no rotation between consecutive passes) through 6 passes, then slightly annealed to obtain the different states of recrystallization. The microstructure was analyzed using high resolution scanning electron microscopy equipped with the local orientation measurements facility. It was observed that the ECAP-processing lead to strong microstructure fragmentation. The as-deformed microstructure was composed of flat (pancake-type) grains with the distance between high angle boundaries in normal direction of about 0.35µm. The low temperature recrystallization led very quickly to microstructure globularization and to their coarsening. After more advanced recrystallization stages the inhomogeneous structure composed of grain classes of different sizes were observed.

Keywords: AA1050 Aluminium alloy; ECAP; Recovery and rekrystallization; Grain growth; EBSD;

One of the goal of this conference was integration PhD students involved in the field of ‘Materials Science’. In this conference about 120 people were attended from seventeen centers in Poland.
There were invited well-known professors who gave lectures on:
- Professor Miroslaw Handke: ‘Silicate materials - from Stone Age to the Present’;
- Professor Marian Szczerka: ‘Tribology - friction and wear in the macro-, micro-and nono-scale’.